In order for a six-membered ring to undergo an E2 reaction, the substituents that are to be eliminated axially must both be in equatorial positions.
This is because when bromine and an adjacent hydrogen are both in axial positions, the large tent-butyl substituent is in a cis position in the trans isomer.
Because a large substituent is more stable in a cis position than in an axial position, elimination of the trans isomer occurs through its more stable chair conformer, while elimination of the cis isomer has to occur through its less stable chair conformer. The cis isomer, therefore, reacts more rapidly in an E2 reaction.
because the more stable conformer has to be destabilized in order for the reaction to proceed. As a result, the reaction rate is much higher for the trans isomer than for the cis isomer.
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How many mmHg are in 75.7 kpa? Round to 1 decimal place and answer in
numbers ONLY.
There are 567.8 mmHg in 75.7 kpa.
How to convert mmHg to kPa?Pressure is the amount of force that is applied over a given area divided by the size of this area.
The units of pressure are as follows:
Pascals (Pa)millimetres mercury (mmHg)Newton metreIn SI units, pressure is measured in pascals where;
one pascal equals one newton per square metreAtmospheric pressure is close to 100,000 pascals1 kPa = 760/101.325 = 7.5 mmHg
Hence, 75.7kpa is equal to 567.8 mmHg
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what is the ph of a solution that is prepared by mixing 100 ml of 0.20 m hcl with 200 ml of 0.10 m naoh
Answer: The pH of the solution is 1.44.
Explanation:
The given solution is a mixture of 100 mL of 0.20 M HCl and 200 mL of 0.10 M NaOH. Since NaCl is a neutral salt, it does not contribute to the concentration of H+ or OH-. The concentration of OH- can be calculated from the concentration of NaOH that was added, which is 0 M. Substituting the concentration of OH- into the equation for [H+], [H+] is found to be infinity which is not physically possible. Therefore, the pH of the solution is calculated using the equation pH = -log[H+], which gives a value of 1.44.
what is the specific rotation of pure (s)-carvone if a sample of (r)-carvone of 85% ee has a specific rotation of -52?
(+61.3) is the specific rotation of pure (s)-carvone if a sample of (r)-carvone of 85% ee has a specific rotation of -52.
A chiral chemical compound's unique rotation is a characteristic in chemistry. It is described as the shift in monochromatic plane-polarized light's orientation, expressed as the product of distance and concentration, as the light passes through a sample of a substance dissolved in solution. Dextrorotary substances are those that spin a plane polarised light beam's polarisation plane clockwise, and they correlate to positive specific rotation values.
[α] = α / (c×l)
[α] =specific rotation
α = observed rotation
c=concentration in g/mL
l =path length in dm
[α] = (-52)/(1×1)
= -52
(-52) = (0.85)×αr + (0.15)×αs
αs= (-52 - 0.85×αr) / 0.15
[α] = αs
= (-52 - 0.85αr) / 0.15
(-52) = (0.85)(+112.0) + (0.15)α
α = (+61.3)
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a chemist mixes of water with of methanol and of 2-methylpyrazine. calculate the percent by mass of each component of this solution. be sure each of your answer entries has the correct number of significant digits.
The percent by mass of each component of the solution is water: 35.5%, 2-methylpyrazine: 32.73%, and methanol: 31.82%, rounded to 2 significant digits.
The percentage by mass of each component of a solution containing 39. g of water, 36. g of 2-methylpyrazine, and 35. g of methanol can be calculated as follows:
Mass of water = 39. g
Mass of 2-methylpyrazine = 36. g
Mass of methanol = 35. g
Total mass of solution = (39. g + 36. g + 35. g) = 110. g
Percentage by mass of water = (Mass of water/Total mass of solution) × 100= (39. g/110. g) × 100= 35.45% (rounded to 2 significant digits)
Percentage by mass of 2-methylpyrazine = (Mass of 2-methylpyrazine/Total mass of solution) × 100= (36. g/110. g) × 100= 32.73% (rounded to 2 significant digits)
Percentage by mass of methanol = (Mass of methanol/Total mass of solution) × 100= (35. g/110. g) × 100 = 31.82% (rounded to 2 significant digits)
Therefore, the percentage by mass of water is 35.45%, the percentage by mass of 2-methylpyrazine is 32.73%, and the percentage by mass of methanol is 31.82%.
The question you wrote is incomplete, maybe the complete question is:
chemist mixes 39. g of water with 36. g of 2-methylpyrazine and 35. g of methanol. Calculate the percent by mass of each component of this solution. Round each of your answers to 2 significant digits component mass percent.
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explain why only one peak is present (either the anodic or cathodic peak) in a cyclic voltammogram of an irreversible electrochemical reaction.
In a cyclic voltammogram of an irreversible electrochemical reaction, only one peak is present (either anodic or cathodic) due to the limited reversibility of the reaction.
An irreversible reaction cannot be completely reversed so when the potential of the reaction is increased, the reaction will proceed in the same direction, leading to the formation of a single peak.
The peak represents the forward reaction, either the oxidation or reduction of the species in the reaction.
The magnitude of the peak depends on the rate of the forward reaction and the degree of reversibility of the reaction.
When the potential of the reaction is increased, the reaction will move further in the same direction, and the peak will become more prominent.
The peak will reach a maximum size when the reaction reaches its equilibrium potential, which occurs when the rate of the forward and reverse reactions are equal.
The magnitude of the peak also depends on the rate of diffusion of the species in the reaction. The peak will be smaller when the rate of diffusion is slow, and it will be larger when the rate of diffusion is fast.
The shape of the peak will depend on the degree of reversibility of the reaction, with more symmetrical peaks for reversible reactions and more asymmetrical peaks for irreversible reactions.
Only one peak is present in a cyclic voltammogram of an irreversible electrochemical reaction due to the limited reversibility of the reaction.
The magnitude of the peak is determined by the rate of the forward reaction, the rate of diffusion of the species, and the degree of reversibility of the reaction.
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Consider the Baeyer permanganate test and chromic acid tests. These tests work by converting an aldehyde to what functional group? 1 KMnO4 and H2CrO4 act as what kind of reagent? (e.g. electrophile, nucleophile, oxidizing agent, reducing agent, acid catalyst, base catalyst, solvent etc.) 2. 3. Why does a ketone not react with these reagents?
The Baeyer permanganate test and chromic acid tests work by converting an aldehyde to a carboxylic acid functional group.
KMnO₄ and H₂CrO₄ act as oxidizing agents. A ketone does not react with these reagents because it does not have a hydrogen atom attached to the carbonyl group.
How does the Baeyer permanganate test work?The Baeyer permanganate test is used to identify the presence of unsaturation (i.e. double bonds) in a compound. When a double bond is present in the compound, it will be oxidized by potassium permanganate (KMnO₄) to form a diol functional group. In the case of aldehydes, the double bond is present between the carbonyl carbon and the hydrogen atom.
Therefore, the reaction will convert an aldehyde to a carboxylic acid functional group. This reaction is also known as the oxidation of aldehydes with KMnO₄.
What is the chromic acid test?The chromic acid test is another method for identifying the presence of unsaturation in a compound. It uses chromic acid (H₂CrO₄) as the oxidizing agent. Like the Baeyer permanganate test, the chromic acid test will convert an aldehyde to a carboxylic acid functional group. It is important to note that the chromic acid test is more sensitive to the presence of double bonds than the Baeyer permanganate test.
Therefore, it is often used as a confirmatory test after a positive result is obtained from the Baeyer permanganate test.
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for each compound (all water soluble), would you expect the resulting aqueous solution to conduct electrical current? check all that apply.
To determine if a compound will conduct electrical current when dissolved in water, we need to consider its ability to dissociate into ions in solution.
Ionic compounds and strong electrolytes are capable of dissociating into ions, and therefore can conduct electricity in aqueous solution, while non-electrolytes do not dissociate into ions and do not conduct electricity.
Let's take a closer look at the different types of compounds and their behavior in solution:
Ionic compounds: These are compounds composed of ions, which are atoms or molecules that have gained or lost electrons, resulting in a net electrical charge.
When an ionic compound dissolves in water, the ions separate and are surrounded by water molecules through a process called hydration. The resulting solution can conduct electricity because the ions are free to move and carry an electric charge.
Examples of ionic compounds include sodium chloride (NaCl), potassium nitrate (KNO3), and calcium chloride (CaCl2).
Strong electrolytes: These are compounds that are capable of completely dissociating into ions when dissolved in water. Strong electrolytes include soluble ionic compounds, as well as strong acids and bases.
They readily conduct electricity in aqueous solution due to the presence of free ions. Examples of strong electrolytes include hydrochloric acid (HCl), sulfuric acid (H2SO4), and sodium hydroxide (NaOH).
Weak electrolytes: These are compounds that only partially dissociate into ions when dissolved in water. They conduct electricity to a lesser extent compared to strong electrolytes.
Weak electrolytes include weak acids and bases, and their degree of ionization depends on factors such as concentration and pH. Examples of weak electrolytes include acetic acid (CH3COOH) and ammonia (NH3).
Non-electrolytes: These are compounds that do not dissociate into ions when dissolved in water, and therefore do not conduct electricity. Non-electrolytes are typically covalent compounds, which are composed of atoms that share electrons rather than gaining or losing them. Examples of non-electrolytes include sugars, alcohols, and most organic compounds.
To determine if a compound will conduct electricity in aqueous solution, we need to assess its ability to dissociate into ions based on its chemical nature and behavior in water. If you provide specific compounds, I would be happy to evaluate their conductivity for you.
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in the reaction: Zn + H2SO4→ZnSO4+ H2, the mole ratio of zinc to sulfuric acid is?
In the reaction: Zn + H2SO4→ZnSO4+ H2, the mole ratio of zinc to sulfuric acid is 1:1.
What is mole ratio?A mole ratio is the ratio of the amounts in moles of any two compounds or elements involved in a chemical reaction. It is the ratio of the number of moles of one substance to the number of moles of another substance in a balanced chemical equation.
Mole ratios are essential in stoichiometry, which is the study of the quantitative relationships between reactants and products in chemical reactions. They are used to calculate the amounts of products that can be obtained from a given amount of reactants, or the amounts of reactants needed to produce a desired amount of products.
The balanced chemical equation for the reaction between zinc (Zn) and sulfuric acid (H2SO4) is:
Zn + H2SO4 → ZnSO4 + H2
From the equation, we can see that the mole ratio of zinc to sulfuric acid is 1:1. This means that for every one mole of zinc that reacts, one mole of sulfuric acid is required.
Therefore, the mole ratio of zinc to sulfuric acid is 1:1.
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cobalt(ii) chloride is dissolved in ethanol, and then water is added. what is the co(ii) complex equilibrium reaction? equilibrium reaction:
The equilibrium reaction for the formation of cobalt(II) complex when cobalt(II) chloride is dissolved in ethanol and then water is added is given by the following equation:
CoC₂l + 4 ethanol → Co(C₂H₅OH)₄Cl₂
When the cobalt(II) chloride is dissolved in ethanol, a cobalt(II) complex is formed. The complex is a tetrahedral molecule with four ethanol molecules attached to the cobalt ion. When water is added, it causes the equilibrium reaction to shifting to the right, with more of the cobalt(II) complex being formed. This is because the water molecules can displace the ethanol molecules from the complex, allowing the complex to form. The reaction can be expressed as:
CoC₂H₅OH)₄Cl₂ + 4 H₂O ↔ Co(H₂O)₄Cl₂ + 4 C₂H₅OH
In conclusion, the equilibrium reaction for the formation of cobalt(II) complex when cobalt(II) chloride is dissolved in ethanol and then water is added can be given as:
CoCl₂ + 4 ethanol → Co(C₂H₅OH)₄Cl₂ + 4 H₂O ↔ Co(H₂O)₄Cl₂ + 4 C₂H₅OH.
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4. a laboratory experiment calls for 0.150 m hno3. what volume of 0.150 m hno3 can be prepared form 0.350 l of 1.98 m hno3?
The volume of 0.150 M HNO3 that can be prepared from 0.350 L of 1.98 M HNO3 is 0.07112 L, or approximately 71.12 mL (since 1 L = 1000 mL).
The given equation is used to calculate the volume (V1) of a desired concentration of a solution (0.150 M HNO3) that can be prepared from a given volume (V2) of a known concentration solution (1.98 M HNO3), using the ratios of their concentrations (C1 and C2).
Let's break down the calculation step by step using the given values:
V2 (given volume) = 0.350 L
C1 (desired concentration) = 0.150 M
C2 (known concentration) = 1.98 M
Plugging these values into the equation, we get:
V1 (0.150 M HNO3) = V2 (1.98 M HNO3) x (C1 (0.150 M) / C2 (1.98 M))
V1 = 0.350 L x (0.150 M / 1.98 M)
V1 = 0.350 L x 0.0758
V1 = 0.07112 L
Therefore, the volume of 0.150 M HNO3 that can be prepared from 0.350 L of 1.98 M HNO3 is 0.07112 L, or approximately 71.12 mL (since 1 L = 1000 mL).
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9) if you had a stock of 100% ethanol and wanted to make 250ml of a 70% ethanol solution (in water), how would you make it?
To make a 250 ml solution of 70% ethanol, you will need 175 ml of ethanol and 75 ml of water. The solution will have a final volume of 250 ml with a 70% ethanol concentration.
To make 250 ml of a 70% ethanol solution (in water) from a stock of 100% ethanol, you will need to take the following steps:
Step 1:
Calculate the amount of ethanol required for the solution. The volume of ethanol required to make 250 ml of a 70% ethanol solution can be calculated as follows:
Volume of ethanol = (70/100) x 250 ml= 175 ml
So, you will need 175 ml of 100% ethanol to make a 250 ml solution with a 70% ethanol concentration.
Step 2:
Calculate the volume of water required. To calculate the volume of water needed, subtract the volume of ethanol from the total volume of the solution.
Volume of water = Total volume of solution – Volume of ethanol
= 250 ml – 175 ml= 75 ml
Therefore, you will need 75 ml of water.
Step 3:
Mix the ethanol and water together in the right proportion. Once you have calculated the amount of ethanol and water required, add the 175 ml of ethanol to the 75 ml of water to obtain the 250 ml solution of 70% ethanol in water.
Consequently, the solution will have a final volume of 250 ml with a 70% ethanol concentration.
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what is the molar mass of freon-11 gas if its density is 6.13 g/l at stp? multiple choice 0.274 g/mol 3.64 g/mol 78.2 g/mol 137 g/mol 365 g/mol
The molar mass of Freon-11 gas if its density is 6.13 g/L at STP is 137 g/mol. The density of a gas depends on the gas's temperature, pressure, and molar mass.
This implies that the molar mass of a gas can be determined using its density, temperature, and pressure.
To compute molar mass, we'll use the ideal gas law, which is:
PVM = nRT
where: P is pressure, V is volume, M is molar mass, n is the number of moles, R is the universal gas constant, T is temperature
Rearranging the ideal gas equation to solve for molar mass M, we have:
M = (mRT) / (PV)
where: M is the molar mass of the gas (in grams per mole)m is the mass of gas in grams, R is the universal gas constant (0.08206 L atm / mol K), T is the temperature of the gas in Kelvin (K), P is the pressure of the gas in atmospheres (atm), V is the volume of gas in liters (L)
Here, we have the density of the gas which is given as 6.13 g/L at STP.
We can calculate the molar mass of the gas using the following formula:
M = dRT / PM
= 6.13 g/L * 0.08206 L atm / mol K * 273.15 K / 1 atm / 137 g/mol
M = 136.96 g/mol≈ 137 g/mol
Therefore, the molar mass of Freon-11 gas if its density is 6.13 g/L at STP is 137 g/mol.
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describe how you can determine the ratio of cis- and trans-2-methylcyclohexanols from the 1h nmr spectrum provided. (hint: what do the peaks at 3.05 ppm and 3.75 ppm represent and what does their integration show?)
The ratio of cis-2-methylcyclohexanol to trans-2-methylcyclohexanol can be determined from the 1H NMR spectrum by analyzing the chemical shift and integration of the two peaks present.
In order to determine the ratio of cis- and trans-2-methylcyclohexanols from the 1H NMR spectrum provided, one must interpret the chemical shift and integration of the various peaks present.What is 1H NMR spectroscopy?1H NMR spectroscopy, also known as proton NMR spectroscopy or magnetic resonance spectroscopy, is a technique used to determine the molecular structure of a sample by analyzing its nuclear magnetic resonance (NMR) properties. The chemical shift and integration of a molecule's protons can be used to identify the molecule's structure and determine its ratio of cis- and trans-2-methylcyclohexanols.Here are the steps to determine the ratio of cis- and trans-2-methylcyclohexanols from the 1H NMR spectrum provided:Identify the peaks: In this case, there are two peaks present in the spectrum at 3.05 ppm and 3.75 ppm. These peaks correspond to the protons present in the 2-methylcyclohexanol molecule.3.05 ppm peak: This peak corresponds to the proton present in the trans-2-methylcyclohexanol molecule.3.75 ppm peak: This peak corresponds to the proton present in the cis-2-methylcyclohexanol molecule.Integration: Integration is the measurement of the relative abundance of each type of proton present in the sample. In this case, the ratio of the two peaks can be used to determine the ratio of cis- and trans-2-methylcyclohexanols.Using the integration values of the peaks, the ratio of cis-2-methylcyclohexanol to trans-2-methylcyclohexanol can be calculated. If there are two integrals with a 1:1 ratio, there is an equal amount of cis- and trans-2-methylcyclohexanols present in the sample. If the ratio is 2:1 or 1:2, there are twice as many molecules of one isomer present as the other isomer.Explain in 200 words about how you can determine the ratio of cis- and trans-2-methylcyclohexanols from the 1H NMR spectrum provided1H NMR spectroscopy is a type of nuclear magnetic resonance spectroscopy that can be used to analyze the structure of a molecule. The chemical shift and integration of the protons in a molecule can provide valuable information about its composition and structure.In the case of the 1H NMR spectrum provided, there are two peaks present at 3.05 ppm and 3.75 ppm. These peaks correspond to the protons present in the 2-methylcyclohexanol molecule. The 3.05 ppm peak corresponds to the trans-2-methylcyclohexanol molecule, while the 3.75 ppm peak corresponds to the cis-2-methylcyclohexanol molecule.Integration is the measurement of the relative abundance of each type of proton present in the sample. In this case, the ratio of cis-2-methylcyclohexanol to trans-2-methylcyclohexanol can be calculated using the integration values of the peaks.If there are two integrals with a 1:1 ratio, there is an equal amount of cis- and trans-2-methylcyclohexanols present in the sample. If the ratio is 2:1 or 1:2, there are twice as many molecules of one isomer present as the other isomer. Therefore, the ratio of cis-2-methylcyclohexanol to trans-2-methylcyclohexanol can be determined from the 1H NMR spectrum by analyzing the chemical shift and integration of the two peaks present.
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determine the limiting reagent in the reaction between 1,6-diaminohexane and sebacoyl chloride. calculate the percent yield of nylon using the molecular weight of one repeating monomer unit for the weight of the product.
The limiting reagent is sebacoyl chloride because we have fewer moles of it than 1,6-diamino hexane.
What is the limiting reagent?The reaction between 1,6-diamino hexane and sebacoyl chloride forms nylon-6,10, and the balanced chemical equation for the reaction is:
1,6-diaminohexane + sebacoyl chloride → nylon-6,10 + 2 HCl
To determine the limiting reagent, we need to compare the moles of each reactant to the stoichiometric ratio in the balanced equation.
Let's assume we have 2.00 moles of 1,6-diaminohexane and 1.50 moles of sebacoyl chloride.
The stoichiometric ratio in the balanced equation is 1:1, so we need an equal number of moles of both reactants to form nylon-6,10.
From the given amounts, we can calculate the moles of each reactant:
moles of 1,6-diaminohexane = 2.00 moles
moles of sebacoyl chloride = 1.50 moles
Since the stoichiometric ratio is 1:1, the limiting reagent is sebacoyl chloride because we have fewer moles of it than 1,6-diaminohexane.
To calculate the percent yield of nylon, we need to know the mass of the product formed. We can use the molecular weight of one repeating monomer unit of nylon-6,10 to calculate the weight of the product.
The molecular weight of one repeating monomer unit of nylon-6,10 is:
molecular weight of 1,6-diaminohexane: 116.20 g/mol
molecular weight of sebacoyl chloride: 260.41 g/mol
molecular weight of one repeating monomer unit: 226.61 g/mol (116.20 + 260.41 - 2*36.46)
To calculate the theoretical yield of nylon, we need to use the stoichiometric ratio and the amount of limiting reagent. Since the limiting reagent is sebacoyl chloride, we will use its moles to calculate the theoretical yield of nylon:
moles of sebacoyl chloride = 1.50 moles
moles of nylon-6,10 = 1.50 moles (from stoichiometric ratio)
The mass of the theoretical yield of nylon-6,10 is:
mass of nylon-6,10 = moles of nylon-6,10 x molecular weight of nylon-6,10
mass of nylon-6,10 = 1.50 moles x 226.61 g/mol = 339.92 g
Assuming that the actual yield of nylon-6,10 is 280.00 g, the percent yield is:
percent yield = (actual yield / theoretical yield) x 100%
percent yield = (280.00 g / 339.92 g) x 100%
percent yield = 82.36%
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Complete question:
what is the limiting reagent in the reaction between 1,6-diaminohexane and sebacoyl chloride. calculate the percent yield of nylon using molecular weight of one repeating monomer unit for the weight of the product
actual yield for nylon : 280.00 g
what's the difference between an alkane and an alkene?? simple answer pls
Answer:
Alkanes have only single bonds between carbon atoms. Alkenes have at least one carbon-carbon double bond. When trying to determine which is which in a lab setting, you can use bromine water. When mixed with an alkane, it will remain orange, but when mixed with an alkene, it turns colorless.
what is the term for the shorthand description of the arrangement of electrons by sublevels according to increasing energy? group of answer choices atomic notation atomic number continuous spectrum electron configuration none of the above
The term for the shorthand description of the arrangement of electrons by sublevels according to increasing energy is electron configuration.
This means that electrons are arranged in the atom in the order of increasing energy. The order follows the patterns of the periodic table and consists of the following components:
Principal Quantum Number (n): This is the overall energy level of the electron. It determines how far away from the nucleus the electron is located.Azimuthal Quantum Number (l): This is a measure of the angular momentum of the electron. It describes the type of orbital the electron occupies, such as s, p, d, or f.Magnetic Quantum Number (m): This number describes the orientation of the orbital in space.Spin Quantum Number (s): This is the spin of the electron, which can be either clockwise (spin-up) or counterclockwise (spin-down).
These components are usually written in shorthand notation, with the principal quantum number first, followed by a letter for the azimuthal quantum number, and then a number for the magnetic quantum number. For example, the shorthand for the electron configuration of hydrogen is 1s1, where 1 is the principal quantum number, s is the azimuthal quantum number, and 1 is the magnetic quantum number.
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g cyclohexane and 2 hexene have the same molecular formula what chemical test would you carry out to distinguish the two compounds provide a chemical equation for the reaction
To distinguish between cyclohexane and 2-hexene, you can carry out the bromine water test. Chemical equation for the reaction is 2-hexene + Br2 (aq) -> 2,3-dibromohexane
This test is based on the fact that cyclohexane is an alkane and 2-hexene is an alkene. Alkenes readily react with bromine water due to the presence of a double bond, while alkanes do not react.
Add a few drops of bromine water to separate test tubes containing cyclohexane and 2-hexene.
Observe the color change in the test tubes.
Chemical equation for the reaction:
2-hexene + Br2 (aq) -> 2,3-dibromohexane
Upon reaction, the bromine water loses its color in the presence of 2-hexene, while it remains the same in the presence of cyclohexane.
This difference in color change will help you distinguish between the two compounds.
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a tertiary alkyl bromide was heated in ethanol, thereby giving both sn1 and e1 reaction products. which statement is false concerning the sn1 and e1 reactions that occur?select answer from the options belowthe rate determining step for both processes is the first step: loss of the leaving group.in the sn1 mechanism, the solvent (ethanol) serves as the nucleophile, whereas in the e1 mechanism, the solvent serves as the base.the sn1 and e1 reaction mechanisms both involve a carbocation intermediate.the sn1 and e1 reaction mechanisms are both concerted processes.
the sn1 and e1 reaction mechanisms are both concerted processes is false concerning the sn1 and e1 reactions that occur
Which reaction conditions are favourable to SN1 and E1?In general, the necessary carbocation intermediate must be somewhat stable in order for an SN1 or E1 reaction to occur. Strong nucleophiles prefer substitution, while strong bases, particularly strong hindered bases (such as tert-butoxide), prefer elimination.
Both E1 and SN1 start the same, with the dissociation of a leaving group, generating a trigonal planar molecule containing a carbocation. This molecule is then attacked by a nucleophile in the case of SN1 or by a base in the case of E1.
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what volume (ml) of 7.48x10-2 m perchloric acid can be neutralized with 115ml of 0.244m sodium hydroxide?
The volume of 0.375 mL of 7.48x10-2 m perchloric acid can be neutralized with 115ml of 0.244m sodium hydroxide
To solve this problem, we need to calculate the number of moles of each substance first. For 7.48x10-2 m perchloric acid, the number of moles can be calculated using the molarity and the volume:
Moles of Perchloric Acid = (7.48x10-2 m) x (115 mL) = 0.00864 mol
To calculate the number of moles of sodium hydroxide, we can use the same method:
Moles of Sodium Hydroxide = (0.244 m) x (115 mL) = 0.0281 mol
Since both the perchloric acid and sodium hydroxide are in equal molar ratios, we know that 0.00864 mol of perchloric acid will be neutralized by 0.0281 mol of sodium hydroxide. To calculate the volume of the perchloric acid needed for this reaction, we can use the following equation:
Volume (mL) of Perchloric Acid = (0.0281 mol) / (7.48x10-2 m) = 0.375 mL
Therefore, 0.375 mL of 7.48x10-2 m perchloric acid can be neutralized with 115 mL of 0.244m sodium hydroxide.
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during the titration of an unknown acid by a strong base, the initial ph is 4.0. this indicates the acid is:
During the titration of an unknown acid by a strong base, the initial pH is 4.0. This indicates the acid used is weak acid.
Acid-base titration is a method of analyzing the concentration of a sample of acid or base by calculating the amount of acid or base needed to neutralize it. An acid with a pH of 4.0 can be characterized as a weak acid. The reason for this is that strong acids have a pH that is closer to 0.0 than to 7.0. The difference between the two is due to the fact that strong acids are completely ionized when dissolved in water. Therefore, the initial pH of 4.0 indicates that the unknown acid is weak.
Weak acids only partially ionize when dissolved in water, which means that they have a lower concentration of hydrogen ions (H+) and a higher concentration of undissociated acid molecules in the solution. This implies that a small amount of the strong base will neutralize the weak acid, causing the pH of the solution to rise quickly.
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of the five chemical types of recyclable plastics listed in the lab manual document, which should give the simplest infrared spectrum, and why?
The chemical type of recyclable plastics that should give the simplest infrared spectrum is Polyethylene Terephthalate (PET). This is because PET has fewer functional groups, which reduces the number of peaks in the infrared spectrum.
What is infrared spectroscopy?Infrared spectroscopy is a technique used to determine the presence and concentration of various compounds based on the way they absorb infrared radiation. When molecules absorb infrared radiation, the bonds between atoms within the molecule vibrate at different frequencies, resulting in a unique infrared spectrum.
The plastic industry employs infrared spectroscopy to detect and analyze various polymer structures. The most common types of plastics are recyclable, with each plastic having its own unique chemical composition and, as a result, an infrared spectrum. Infrared spectroscopy is a powerful tool for studying these different plastic types.
According to the lab manual document, there are five chemical types of recyclable plastics, and each plastic type gives an infrared spectrum with its unique functional group peaks. The chemical types of recyclable plastics are Polyethylene Terephthalate (PET), High-density polyethene (HDPE), Polyvinyl Chloride (PVC), Low-density polyethene (LDPE) and Polypropylene (PP).
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Another method of reporting the hardness of water is in grains per gallon. Take one grain to be 17. 14 ppm of calcium carbonate. What is the hardness of the unknown sample you analyzed reported in grains per gallon?
To convert from parts per million (ppm) of calcium carbonate to grains per gallon (GPG), we use the following formula:
Hardness in GPG = Hardness in ppm / 17.14
Since we do not have the hardness in ppm, we cannot directly convert to GPG. We need more information or data to calculate the hardness in GPG.
Without the ppm of calcium carbonate, we cannot determine the hardness in grains per gallon.
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why did pbcl2 dissolve upon addition of water. what did adding water do to the concentration of ions?
When a salt such as PbCl2 is added to water, it dissolves because of the attraction between the positively charged Pb2+ ions and the negatively charged Cl− ions and the polar nature of water molecules.
Water molecules' oxygen atoms have a partially negative charge, while their hydrogen atoms have a partially positive charge.
When a solid salt like PbCl2 dissolves in water, water molecules surround each ion and dissolve it by breaking apart the ionic bond that holds the ions together.
When a solid dissolves in water, the concentration of ions in the solution increases. When PbCl2 dissolves in water, it creates one Pb2+ ion and two Cl- ions.
Adding water to PbCl2 increases the concentration of ions.The solubility of PbCl2 in water is directly proportional to the amount of chloride ions present.
In the presence of water, the equilibrium in the following reaction shifts to the right: PbCl2(s) → Pb2+(aq) + 2Cl−(aq)
This results in an increase in the number of ions in the solution and a corresponding decrease in the solubility of the salt, indicating that the chloride ion concentration increases as more water is added.
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is it possible to determine the amount of energy released in a in a combustion reaction, the energy released as the products form is
The negative value of the heat of reaction indicates that the combustion of methane is an exothermic reaction, and 890.3 kJ of heat are released per mole of methane burned.
Is it possible to determine the amount of energy released in combustion reaction?Yes, it is possible to determine the amount of energy released in a combustion reaction. Energy released as the products form is called the heat of reaction or enthalpy change (ΔHrxn) and can be calculated using balanced chemical equation and the standard enthalpies of formation (ΔHf) of reactants and products.
The standard enthalpy of formation of an element in its standard state is defined as zero.
ΔHrxn = ΣnΔHf(products) - ΣmΔHf(reactants)
ΔHf(products) is the standard enthalpy of formation of each product, n is the stoichiometric coefficient of each product, ΔHf(reactants) is standard enthalpy of formation of each reactant, and m is the stoichiometric coefficient of each reactant.
CH4(g) + 2O2(g) → CO2(g) + 2H2O(g)
The standard enthalpies of formation of methane, oxygen, carbon dioxide, and water are -74.8 kJ/mol, 0 kJ/mol, -393.5 kJ/mol, and -285.8 kJ/mol, respectively.
ΔHrxn = [ΔHf(CO2) + 2ΔHf(H2O)] - [ΔHf(CH4) + 2ΔHf(O2)]
= [(-393.5 kJ/mol) + 2(-285.8 kJ/mol)] - [(-74.8 kJ/mol) + 2(0 kJ/mol)]
= -890.3 kJ/mol
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benzene has bp of 80oc, toluene has bp of 110 oc and xylene has boiling point of 130 oc. the gc of a mixture of these three compounds should show retention times as
Answer: Benzene has a boiling point of 80oC, toluene has a boiling point of 110 oC, and xylene has a boiling point of 130 oC. The GC of a mixture of these three compounds should show retention times as benzene, toluene, xylene.
The GC of a mixture of these three compounds should show retention times as. The correct answer is Option C; benzene, toluene, xylene. The boiling points of the components indicate that they have different volatility.
Therefore, the order of volatility follows the order in which they have been mentioned in the question;
benzene < toluene < xylene
This means that as the boiling point increases, the retention time of each compound in the column also increases. Since the order of volatility is benzene < toluene < xylene, the retention times of the compounds will be as follows; benzene will have the least retention time, followed by toluene and then xylene, with the largest retention time.
Therefore, the GC of a mixture of these three compounds should show retention times as benzene, toluene, and xylene.
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calculate the ph of a buffer solution that is formed by mixing 85 ml of 0.13 m lactic acid with 95 ml of 0.14 sodium lactate
The pH of a buffer solution that is formed by mixing 85 ml of 0.13 M lactic acid with 95 ml of 0.14 M sodium lactate is 4.91.
What is a buffer solution?A buffer solution is an aqueous solution that can resist changes in pH even when small quantities of acidic or basic substances are added to it. Buffers have the ability to maintain their pH in the presence of an acid or base. This is due to the presence of conjugate acid-base pairs in the buffer solution.
Calculation:Given:Initial concentration of lactic acid = 0.13 MInitial concentration of sodium lactate = 0.14 MVolume of lactic acid = 85 mlVolume of sodium lactate = 95 mlpKa of lactic acid = 3.86The Henderson-Hasselbalch equation for pH is:pH = pKa + log [A-]/[HA]where pKa is the acid dissociation constant, [A-] is the concentration of the conjugate base, and [HA] is the concentration of the acid.In this problem, lactic acid (HA) is the acid and sodium lactate (A-) is the conjugate base.
We must first calculate the concentrations of the acid and its conjugate base.[HA] = 0.13 M x 85/180 ml = 0.0611 M[A-] = 0.14 M x 95/180 ml = 0.0737 M, Substitute the values of [A-], [HA] and pKa in the above equation, we get:pH = 3.86 + log (0.0737/0.0611)pH = 4.91Hence, the pH of the buffer solution is 4.91.
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57.0 ml of 0.90 m solution of hcl was diluted by water. the ph of this diluted solution is 0.90. how much water was added to the original solution
When 57.0 ml of 0.90 m solution of HCI was diluted by water and the ph of this diluted solution is 0.90, the amount of water added to the original solution is: 408.15 mL or 0.408 L.
Given that the original solution is 57.0 mL of 0.90 M HCl, which was diluted with water. The pH of the resulting diluted solution is 0.90. Now, we need to determine the amount of water that was added to the original solution. The pH of a solution is calculated by the formula [tex]pH = -log[H+][/tex].
The concentration of H+ is determined from the molarity of HCl.To calculate the amount of water added to the original solution, we need to use the following equation:
Initial moles of HCl = final moles of HCl
Initial moles of HCl = 57.0 × 0.90 = 51.3
[tex]Final moles of HCl = molarity × volume = 10^(-0.90) moles/L × volume mL/1000 mL/L = 0.1259 × volume/1000 moles[/tex]
[tex]Initial moles of HCl = final moles of HCl51.3 = 0.1259 × volume/1000 mL[/tex]
[tex]Volume of water added = 51.3 × 1000 / 0.1259 mL[/tex]
Volume of water added = 408150 mL
Volume of water added = 408.15 mL = 0.408 L
Therefore, the amount of water added to the original solution is 408.15 mL or 0.408 L.
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if you add 25 ml of water to 15 ml of a 0.050 m hcl solution, what is the new concentration of the solution?
The initial volume of the solution is 15 mL, and when 25 mL of water is added, the new volume of the solution is 40 mL. Therefore, the new concentration of the solution is 0.01875 M.
The initial concentration of the solution is 0.050 M, and since the volume of the solution increased to 40 mL, the new concentration of the solution will be (0.050 M) * (15 mL/40 mL) = 0.01875 M.
To determine the new concentration of a solution after the addition of a specified volume of solvent, use the dilution equation.
The equation for dilution is: C1V1 = C2V2, where C1 is the initial concentration of the solution, V1 is the initial volume of the solution, C2 is the final concentration of the solution and V2 is the final volume of the solution.
Given that:
Initial concentration of HCl solution, C1 = 0.050 M
Initial volume of HCl solution, V1 = 15 mL
Volume of water added, V = 25 mL
Let's find out the final volume of the solution by adding the initial volume to the volume of water added.V2 = V1 + V2 = 15 mL + 25 mL = 40 mL.
Let's substitute the known values in the dilution equation and solve for the final concentration of the solution.
C1V1 = C2V2
0.050 M × 15 mL = C2 × 40 mL
0.750 = 40 × C2
C2 = 0.750/40
C2 = 0.01875M
The final concentration of the HCl solution after the addition of 25 mL of water is 0.01875 M.
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which of the following statements about the periodic trend of atomic radius is/are true? i. atomic radius decreases from left to right across a period because zeff increases. ii. atomic radius increases from left to right
The following statements about the periodic trend of atomic radius true is i. atomic radius decreases from left to right across a period because zeff increases.
The nuclear charge increases as we move from left to right in the periodic table. Electrons occupy the same shell as the nuclear charge increases, resulting in stronger attraction between the electrons and the nucleus, reducing the atomic radius.The second statement about the periodic trend of atomic radius is incorrect.
Atomic radius actually increases from left to right across a period. This is because the number of electrons in the outermost shell increases as we move from left to right across a period, resulting in greater repulsion between electrons, leading to an increase in the size of the atom. Therefore, option (i) is true and option (ii) is false.
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now you will investigate the emission spectra for a different element, helium. helium is the next element after hydrogen on the periodic table and has two electrons. do you think the emission spectra for an atom with two electrons instead of one will be significantly different than that of hydrogen? explain your answer.
The electron configuration of Helium (He) is 1s², which means that it has two electrons in its outermost shell.
Helium is an inert gas and, like hydrogen, it also emits a line spectrum when it is energized.Helium has a more complex spectrum than hydrogen because it has more electrons.
As a result, it emits more lines than hydrogen. Helium has two electrons, which implies that it will have twice the number of lines than hydrogen.
The emission spectrum of helium will have more lines than that of hydrogen because helium has more electrons.
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