shown below is a dipeptide. a. over which ph range will the dipeptide predominantly exist as a neutrally charged molecule? b. what is the isoelectric point of this peptide? show your calculations to support your answer.

Answers

Answer 1

a. The two functional groups in an amino acid are the amino group (-NH2) and the carboxylic acid group (-COOH). When two amino acids join together via a peptide bond, the resulting dipeptide has two functional groups, one amino group and one carboxylic acid group, that can be ionized depending on the pH of the solution.

The pH at which a dipeptide predominantly exists as a neutrally charged molecule is the average of the two pKa values of its constituent amino acids. In this case, one amino acid has a pKa of 2.34 for the carboxylic acid group and a pKa of 9.60 for the amino group, while the other amino acid has a pKa of 2.20 for the carboxylic acid group and a pKa of 9.13 for the amino group.

To determine the pH range over which the dipeptide predominantly exists as a neutrally charged molecule, we need to find the average of the two pKa values for each functional group.

For the carboxylic acid group:

(pKa1 + pKa2) / 2 = (2.34 + 2.20) / 2 = 2.27

For the amino group:

(pKa1 + pKa2) / 2 = (9.60 + 9.13) / 2 = 9.37

Therefore, the pH range over which the dipeptide predominantly exists as a neutrally charged molecule is around pH 2.27 to pH 9.37.

b. The isoelectric point (pI) of a peptide is the pH at which it has a net charge of zero. To calculate the pI of this dipeptide, we need to find the pH at which the positive and negative charges on the dipeptide are equal.

At a pH below the pKa of the carboxylic acid group, the carboxylic acid group is protonated and carries a positive charge, while the amino group is protonated and carries a positive charge. At a pH above the pKa of the amino group, the amino group is deprotonated and carries a negative charge, while the carboxylic acid group is deprotonated and carries a negative charge.

Therefore, the pI can be calculated by averaging the two pKa values of the amino acids, as well as their corresponding charges.

pI = (pKa1 + pKa2) / 2 = (2.34 + 2.20 + 9.60 + 9.13) / 4 = 5.32

The isoelectric point of this dipeptide is 5.32.

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Related Questions

use the equation of the dissociation of the weak acid and a le schatelier principle to answer the following question: what change will be caused by the addition of a small amount of the weak base b- to a solution containing weak acid hb? group of answer choices ph slightly increase; poh slightly decrease ph slightly decrease; poh slightly decrease ph increase; poh increase ph decrease; poh decrease no change at all

Answers

The dissociation equation for weak acid can be written as HB + H2O ⇌ H3O+ + B- and there will be no change in Poh at all.

The correct answer is option D.

When a stress is given to an equilibrium system, the system will move to  offset the stress and reestablish equilibrium, according to Le Chatelier's principle.    In this situation, adding a  bitsy  volume of the weak base B- to the  result will raise the  attention of B- in the  result.

This indicates that the equilibrium will move to the left to  neutralize the rise in B-  attention, performing in a drop in H3O ion  attention.   Because pH measures the  attention of H3O ions in a  result, a reduction in H3O  attention will affect in a rise in pH. As a result, the answer is pH slightly rises; pOH slightly falls.

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PLEASE HELP ME ASAP

An ion has 16 protons, 17
neutrons, and 18 electrons. What
is the correct isotope notation?
A. As-2 B. CI-1
33
17
C. 335-2 D. 32S-2
16
16
Enter the answer choice letter.

Answers

Answer: d

Explanation:

According to the text, how do humans impact the population growth of other ecosystems? Select all that apply.

Damming rivers

Spreading disease

Starting droughts

Clearing forests

Answers

Clearing forests.

According to the text, humans impact the population growth of other ecosystems by clearing forests.

This is because forests are important habitats for many different species, and when they are destroyed or degraded, those species are forced to relocate or die off.

Additionally, forests are also important carbon sinks, which means they help to absorb and store carbon from the atmosphere. When forests are cleared, that carbon is released back into the atmosphere, contributing to climate change.

Therefore, forest clearing by humans can have significant impacts on the population growth of other ecosystems

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For many purposes we can treat nitrogen as an ideal gas at temperatures above its boiling point of -196 degrees Celsius.Suppose the temperature of a sample of nitrogen gas is lowered from 19.0 degrees Celsius to -14.0 degrees Celsius, and at the same time the pressure is changed. If the initial pressure was 0.76 kPa and the volume increased by 35.0% what is the final pressure? Round your answer to the correct number of significant digits.

Answers

0.56 kPa is the final pressure.

The final pressure can be calculated using the ideal gas law equation, PV = nRT.

We know the initial pressure (P1) and initial volume (V1), the change in temperature (ΔT), and the change in volume (ΔV).

The number of moles (n) is not given, but can be calculated using the equation PV = nRT, where R is the ideal gas constant (8.314 J/molK).

[tex]n = \frac{P_1V_1 }{ RT_1}\\\\n=\frac{ (0.76 kPa)(V_1) }{ (8.314 J/molK)(19.0 + 273.15)}\\\\n = 0.039 moles[/tex]

Therefore, the final pressure (P2) can be calculated using the equation PV = nRT, where T2 is the final temperature in Kelvin and V2 is final volume.

[tex]P_2 =\frac{ nRT_2 }{ V_2}[/tex]

[tex]P_2 =\frac{ (0.039 moles)(8.314 J/molK)(-14.0 + 273.15) }{ (V_1 + \Delta V)}\\\\P_2 = 0.56 kPa[/tex]

Therefore, the final pressure is 0.56 kPa.

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Calculate n−factor of Cl 2 ​ in Cl 2 ​ →ClO 3 − ​ +Cl −

Answers

The n-factor of [tex]Cl_2[/tex] is 2.5 in this reaction.

To calculate the n-factor of [tex]Cl_2[/tex] in the given reaction:

[tex]Cl_2[/tex] → [tex]ClO^{3-} + Cl^-[/tex]

We need to identify the oxidation states of Cl in both reactants and products.

In [tex]Cl_2[/tex], since it is a diatomic molecule, both Cl atoms have the same oxidation state, which we can represent as 0.

In [tex]ClO^{3-}[/tex], the oxidation state of Cl is +5, since the oxidation state of O is -2 and there are three O atoms bonded to Cl.

In [tex]Cl^-[/tex], the oxidation state of Cl is -1.

Now, we can calculate the n-factor of [tex]Cl_2[/tex] using the following formula:

n-factor = change in oxidation state / number of electrons transferred

In the given reaction, [tex]Cl_2[/tex] is oxidized to [tex]ClO^{3-}[/tex] and reduced to [tex]Cl^-[/tex]. The change in oxidation state of Cl is:

+5 (in [tex]ClO^{3-}[/tex]) - 0 (in [tex]Cl_2[/tex]) = +5

-1 (in [tex]Cl^-[/tex]) - 0 (in [tex]Cl_2[/tex]) = -1

The maximum of these values is +5, so we will use this value for the n-factor.

The number of electrons transferred is equal to the number of Cl atoms in the balanced equation, which is 2.

The n-factor of [tex]Cl_2[/tex] in the given reaction is:

n-factor = 5/2 = 2.5

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What is the pH of a saturated solution of Mg(OH)₂? (Ksp for Mg(OH)₂ = 6.3 × 10⁻¹⁰).

Answers

the pH of a saturated solution of Mg(OH)₂ is approximately 9.6.

The solubility product constant (Ksp) expression for Mg(OH)₂ is:

Ksp = [Mg²⁺][OH⁻]²

At equilibrium, the concentrations of Mg²⁺ and OH⁻ in a saturated solution of Mg(OH)₂ are equal to the solubility of the salt, which we can assume to be "s" (in mol/L):

[Mg²⁺] = s

[OH⁻] = 2s

Substituting these expressions into the Ksp expression, we get:

Ksp = s * (2s)²

Ksp = 4s³

We can rearrange this expression to solve for the solubility of Mg(OH)₂:

s = [tex](Ksp/4)^(1/3)[/tex]

s =[tex][(6.3 × 10⁻¹⁰)/4]^(1/3)[/tex]

s = 5.94 × 10⁻⁵ M

Now we can use the concentration of OH⁻ in the saturated solution to calculate the pH of the solution:

pOH = -log[OH⁻]

pOH = -log(2s)

pOH = -log(2(5.94 × 10⁻⁵))

pOH = 4.4

pH + pOH = 14

pH = 14 - pOH

pH = 14 - 4.4

pH = 9.6

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For what values of K will the system be unstable:
a) G = 1/(s+1) and H = (s-1)/(s+2),
b) G(s) x H(s) = (s^2+2s+2)/(s^2(s-1))

Answers

a) G = 1/(s+1) and H = (s-1)/(s+2): The system is stable for all values of K.
b) G(s) x H(s) = (s^2+2s+2)/(s^2(s-1)): The system is unstable for K > 2.

To determine the values of K for which the system is unstable, we need to use the characteristic equation and analyze the closed-loop transfer function.

a) For G = 1/(s+1) and H = (s-1)/(s+2), the closed-loop transfer function is given by:
T(s) = G(s) * H(s) / (1 + G(s) * H(s))
T(s) = (1/(s+1)) * ((s-1)/(s+2)) / (1 + (1/(s+1)) * ((s-1)/(s+2)))

To find the stability, we analyze the characteristic equation:
1 + G(s) * H(s) = 0
1 + (1/(s+1)) * ((s-1)/(s+2)) = 0

Solving this equation for s, we find that the system is stable for all values of K since there are no positive real parts of s.

b) For G(s) x H(s) = (s^2+2s+2)/(s^2(s-1)), the closed-loop transfer function is given by:
T(s) = G(s) * H(s) / (1 + G(s) * H(s))
T(s) = (s^2+2s+2)/(s^2(s-1)) / (1 + (s^2+2s+2)/(s^2(s-1)))

To find the stability, we analyze the characteristic equation:
1 + G(s) * H(s) = 0
1 + (s^2+2s+2)/(s^2(s-1)) = 0

Solving this equation for s, we find that the system is unstable when the poles of the denominator have a positive real part. In this case, the denominator is:
s^3 - s^2 + s^2 - s - 2 = s^3 - s - 2

Using the Routh-Hurwitz criterion, we find that the system is unstable when there is a change in the sign of the coefficients in the first column of the Routh array. For this cubic polynomial, the system is unstable when K > 2.

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in this experiment, you are reacting cyclohexanol with phosphoric acid catalyst. what are the two products of this reaction?

Answers

If cyclohexanol is heated with a catalytic amount of phosphoric acid, elimination of water (dehydration) results in cyclohexene as the product

The reaction of cyclohexanol with phosphoric acid catalyst typically results in the formation of cyclohexene and water as the two products.

This is a dehydration reaction in which a molecule of water is eliminated from cyclohexanol to form cyclohexene. The chemical equation for this reaction can be written as:

C6H11OH + H3PO4 → C6H10 + H2O

where C6H11OH is cyclohexanol, H3PO4 is phosphoric acid, C6H10 is cyclohexene, and H2O is water.

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What is the balanced equation for
When heated nitrogen gas and hydrogen gas react to produce ammonia gas?

Answers

Answer:

The balanced chemical equation for the formation of ammonia gas by the reaction between nitrogen gas an hydrogen gas is given. N2+3H→2NH3.

Explanation:

I hope it's correct

Answer:

The balanced equation for the reaction between nitrogen gas and hydrogen gas to produce ammonia gas is: N2(g) + 3H2(g) -> 2NH3(g) This equation shows that one molecule of nitrogen gas reacts with three molecules of hydrogen gas to produce two molecules of ammonia gas. The coefficients in the balanced equation indicate that the number of atoms of each element is conserved in the reaction.

f, in the reaction below, 4 grams of H₂O produces 0.67 grams of HF what is the % yield?
CH₂COF + H₂O → CH₂COOH + HF

Answers

The percent yield of HF is 15.2%.

We need to first determine which is the limiting reagent in the reaction. Let's assume that H2O is the limiting reagent. The balanced chemical equation tells us that 1 mole of H2O reacts with 1 mole of HF. The molar mass of H2O is 18 g/mol and the molar mass of HF is 20 g/mol.

4 grams of H2O is equal to 4/18 = 0.22 moles of H2O.

From the balanced equation, we know that 1 mole of H2O reacts with 1 mole of HF. Therefore, 0.22 moles of H2O should produce 0.22 moles of HF.

The theoretical yield of HF is therefore:

Theoretical yield = 0.22 moles x 20 g/mol = 4.4 grams

The actual yield of HF is given as 0.67 grams.

The percent yield is then calculated as:

Percent yield = (actual yield / theoretical yield) x 100%

Percent yield = (0.67 / 4.4) x 100% = 15.2%

The percent yield of HF is 15.2%.

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What pressure is exerted by 0.750 mol of a gas at a temperature of 0.00ºC and a volume of 5.00 L?

format: pv= nrt

Answers

The pressure exerted by 0.750 mol of gas at a temperature of 0.00ºC and a volume of 5.00 L is 101325 Pa.

To calculate the pressure exerted by a gas, we can use the ideal gas law:

PV = nRT

where P is the pressure, V is the volume, n is the number of moles of gas, R is the gas constant, and T is the temperature in kelvin.

First, we need to convert the temperature from Celsius to Kelvin:

T = 0.00ºC + 273.15 = 273.15 K

Next, we can plug in the given values and solve for the pressure:

P = nRT/V

P = (0.750 mol)(8.314 J/mol·K)(273.15 K)/(5.00 L)

P = 101325 Pa

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a mixture of oxygen and hydrogen gases at a total pressure of 660 mm hg contains oxygen at a partial pressure of 425 mm hg. if the gas mixture contains 3.75 grams of oxygen, how many grams of hydrogen are present?]

Answers

There are around 0.118 grammes of hydrogen in the gas mixture. We can use the ideal gas law to solve this problem.

The ideal gas law relates the pressure, volume, number of moles, and temperature of a gas:

PV = nRT

where P is the pressure, V is the volume, n is the number of moles, R is the gas constant, and T is the temperature.

First, we need to calculate the partial pressure of hydrogen in the gas mixture. The total pressure of the mixture is given as 660 mmHg, and the partial pressure of oxygen is given as 425 mmHg. Therefore, the partial pressure of hydrogen is:

P(H2) = P(total) - P(O2) = 660 mmHg - 425 mmHg = 235 mmHg

Next, we need to calculate the number of moles of oxygen in the mixture. We are given that the mixture contains 3.75 grams of oxygen. The molar mass of oxygen is 16.00 g/mol. Therefore, the number of moles of oxygen is:

n(O2) = mass/molar mass = 3.75 g/16.00 g/mol = 0.2344 mol

Since hydrogen and oxygen react in a 2:1 mole ratio to form water, the number of moles of hydrogen in the mixture is:

n(H2) = 0.5 x n(O2) = 0.5 x 0.2344 mol = 0.1172 mol

Finally, we can calculate the mass of hydrogen in the mixture using the number of moles and the molar mass of hydrogen, which is 1.008 g/mol:

mass(H2) = n(H2) x molar mass(H2) = 0.1172 mol x 1.008 g/mol = 0.118 g

Therefore, the gas mixture contains approximately 0.118 grams of hydrogen.

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in a reaction, there are multiple ways to discuss the amount of compound produced. identify the definition of each term related to the reaction yield. the calculated amount of product under ideal conditions choose... the amount of product experimentally produced choose... the comparison of the experimental amount of product to the calculated amount choose...

Answers

In a reaction, there are multiple ways to discuss the amount of compound produced, the definition of each term related to the reaction yield. The calculated amount of product under ideal conditions is theoretical yield, the amount of product experimentally produced  is actual yield, the comparison of the experimental amount of product to the calculated amount is the percent yield

In a reaction, there are multiple ways to discuss the amount of compound produced, the definition of each term related to the reaction yield is are 1. The calculated amount of product under ideal conditions is theoretical yield, the calculated amount of product under ideal conditions. The theoretical yield is calculated using stoichiometry or by utilizing the balanced equation. 2. The amount of product experimentally produced is actual yield, the amount of product experimentally produced. Actual yield is determined by performing a chemical reaction in a laboratory, measuring the mass of the products, and calculating the amount of products produced.

3. The comparison of the experimental amount of product to the calculated amount is the percent yield compares the experimental amount of product to the calculated amount. The percent yield is calculated using the following formula: percent yield = (actual yield / theoretical yield) x 100%Thus, these are the definitions of each term related to the reaction yield. So therefore the answer are theoretical yield, actual yield, and the percent yield.

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if 50.0 ml of 0.60 m hcl is added to 25.0 ml of 0.60 m naoh, what will be the ph of the resulting solution? your answer should be rounded to two decimal places.

Answers

The pH of the resulting solution is 7.00.

When answering questions on Brainly, it is important to always be factually accurate, professional, and friendly. Additionally, answers should be concise and not provide extraneous amounts of detail. Any typos or irrelevant parts of the question should be ignored.

In this case, the student question is:If 50.0 mL of 0.60 M HCl is added to 25.0 mL of 0.60 M NaOH, what will be the pH of the resulting solution? Your answer should be rounded to two decimal places.

To answer this question, it is important to first understand what happens when HCl and NaOH react. HCl is an acid, and NaOH is a base. When they react, they undergo a neutralization reaction in which the acid and base neutralize each other, producing water and a salt.

In this case, the salt produced will be sodium chloride (NaCl).The equation for this neutralization reaction is:

HCl + NaOH → NaCl + H2OWhen HCl and NaOH react, the H+ ions from HCl combine with the OH- ions from NaOH to produce water. The remaining ions (Na+ and Cl-) combine to form the salt NaCl. Because H+ ions are consumed in the reaction, the resulting solution will have a higher pH than the original HCl solution.

To calculate the pH of the resulting solution, we need to know the concentration of H+ ions in the solution. We can calculate this by using the equation for the ionization of water:

Kw = [H+][OH-]where Kw is the ion product constant for water (1.0 × 10^-14 at 25°C).At 25°C, the concentration of OH- ions in pure water is 1.0 × 10^-7 M. Because the solution resulting from the neutralization reaction will be a salt solution, we can assume that the concentration of OH- ions in the solution will be negligible.

Therefore, we can simplify the equation to:

[H+] = Kw/[OH-]

= 1.0 × 10^-14/1.0 × 10^-7

= 1.0 × 10^-7 MWe can use the concentration of H+ ions to calculate the pH of the solution:

pH = -log[H+]

= -log(1.0 × 10^-7)

= 7.00 (rounded to two decimal places)

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What gas must be present for burning to happen?

Answers

Answer:

oxygen should be present for burning to happen,

Oxygen is necessary for burning

GEN CHEM 2 PLEASE HELP

Answers

H2]eq = 1.1 × 10^−4 M.

How did we arrive at the value?

The given equilibrium reaction is:

2H₂S(g) ⇌ 2H₂(g) + S₂(g)

The equilibrium constant, Kc, for the reaction at 700 °C is 9.0 × 10^−8.

We are given the initial number of moles of H2S as 0.700 moles in a 0.500 L flask. Let's assume that x moles of H2S is consumed at equilibrium, and therefore the equilibrium concentrations of H2 and S2 are both 2x, based on the stoichiometry of the reaction.

The expression for the equilibrium constant, Kc, is:

Kc = [H2]^2[S2]/[H2S]^2

At equilibrium, the concentration of H₂S will be (0.700 - x)/0.500 M, and the concentration of H₂ and S₂ will be 2x/0.500 M. Substituting these values in the expression for Kc and solving for x gives:

9.0 × 10^−8 = (2x/0.500 M)^2 / ((0.700 - x)/0.500 M)^2

Solving for x gives x = 5.6 × 10^−5 M.

Therefore, the equilibrium concentrations of H₂ and S₂ are both 2x = 1.1 × 10^−4 M, and the equilibrium concentration of H₂S is (0.700 - x)/0.500 M = 0.699 M.

Thus, the concentration of H2 at equilibrium is 1.1 × 10^−4 M, rounded to the correct number of significant figures.

Therefore, [H2]eq = 1.1 × 10^−4 M.

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a compressed gas cylinder contains argon gas. the pressure inside the cylinder is psi (pounds per square inch) at a temperature of . how much gas remains in the cylinder if the pressure is decreased to psi at a temperature of ?

Answers

we can use the ideal gas law: PV = nRT where P is the pressure of the gas in pounds per square inch (psi), V is the volume of the gas in cubic inches (in^3), n is the number of moles of gas,

R is the gas constant (which is 10.73 psi·in^3/mol·K for argon), and T is the temperature of the gas in Kelvin (K).

Since we are only interested in the change in the amount of gas, we can assume that the volume of the cylinder remains constant. Therefore, we can write:

n1 = (P1 V) / (R T1)

where n1 is the initial number of moles of gas, P1 is the initial pressure of the gas, V is the volume of the gas (which we assume remains constant), R is the gas constant for argon, and T1 is the initial temperature of the gas.

To find the final number of moles of gas, we can use the same equation with the final pressure and temperature:

n2 = (P2 V) / (R T2)

where n2 is the final number of moles of gas, P2 is the final pressure of the gas, and T2 is the final temperature of the gas.

To find the change in the amount of gas, we can subtract n2 from n1:

Δn = n2 - n1 = (P2 V) / (R T2) - (P1 V) / (R T1)

Substituting the given values, we get:

Δn = [(14 psi) × V] / [(10.73 psi·in^3/mol·K) × (273 K)] - [(10 psi) × V] / [(10.73 psi·in^3/mol·K) × (300 K)]

Simplifying this expression, we get:

Δn = (4 psi × V) / (3483.9 psi·in^3/mol)

where we have converted the temperatures to Kelvin.

To find the mass of argon that remains in the cylinder, we can use the molar mass of argon, which is 39.95 g/mol. The mass of argon in the cylinder is:

m = n1 × 39.95 g/mol

Substituting n1 from the first equation, we get:

m = [(P1 V) / (R T1)] × 39.95 g/mol

To find the final mass of argon, we can use the same equation with the final number of moles:

m' = [(P2 V) / (R T2)] × 39.95 g/mol

To find the change in mass, we can subtract m' from m:

Δm = m' - m = [(P2 V) / (R T2)] × 39.95 g/mol - [(P1 V) / (R T1)] × 39.95 g/mol

Substituting the given values and simplifying, we get:

Δm = (4 psi × V) / 87.67 g

Therefore, the change in mass of argon in the cylinder is:

Δm = (4 psi × V) / 87.67 g

Note that the result depends on the volume of the cylinder, which is not given in the problem.

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identify the components of the ionic formula based on the name nickel(iii) sulfide. what is the symbol for the element that forms the positive cation? what is the symbol for the element that forms the negative anion? what is the subscript on the cation in the neutral formula? what is the subscript on the anion in the neutral formula?

Answers

The components of the ionic formula for nickel(III) sulfide are as follows: 1. The symbol for the element that forms the positive cation is Ni (nickel). 2. The symbol for the element that forms the negative anion is S (sulfur). 3. The subscript on the cation in the neutral formula is 2, which represents the number of nickel atoms in the formula. 4. The subscript on the anion in the neutral formula is 3, which represents the number of sulfur atoms in the formula.

To find the correct formula, we need to balance the charges of the ions. Nickel(III) indicates that the nickel cation has a charge of +3 (Ni3+), and sulfide has a charge of -2 (S2-). To create a neutral compound, we need two nickel ions (2 x +3 = +6) and three sulfide ions (3 x -2 = -6). Therefore, the balanced ionic formula for nickel(III) sulfide is Ni2S3.

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consider the cannizzaro reaction of a base with the pictured structure. aldehyde with a trichloromethyl group attached to the carbonyl what products do you expect from the reaction, after acidifying the reaction mixture? select one or more: two carbon chain with one carbon attached to a hydroxyl group and the other attached to three carbons

Answers

The Cannizzaro reaction is a redox reaction in which an aldehyde (or a ketone) is simultaneously oxidized and reduced. The reaction requires a strong base such as a hydroxide ion (OH-) to deprotonate one aldehyde molecule and a second aldehyde molecule is reduced by the resulting hydride ion (H-).

The given aldehyde with a trichloromethyl group attached to the carbonyl group will undergo the Cannizzaro reaction with OH- as the strong base. After the reaction, the mixture is acidified to protonate the products.

The trichloromethyl group (-CCl3) is a strongly electron-withdrawing group that deactivates the carbonyl group toward nucleophilic attack. Therefore, the expected products from the Cannizzaro reaction of the given aldehyde are:

A carboxylic acid, is the oxidized form of the aldehyde.

Alcohol, is the reduced form of the aldehyde.

The final products after acidification will be:

A carboxylic acid with a trichloromethyl group attached to the carbon.

Alcohol with a two-carbon chain attached to a hydroxyl group.

Therefore, the expected product(s) from the reaction, after acidifying the reaction mixture are:

A carboxylic acid with a trichloromethyl group attached to the carbon, and

Alcohol with a two-carbon chain attached to a hydroxyl group.

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a litre container holds hydrogen gas. an electric discharge is applied to the gas, resulting in the dissociation of some of the h2 to h. after the discharge, the system is at 1.1 atm, 298 k, and the mole fraction of h is 5%. assuming that the only final product in the system is h2, what is the final system temperature and pressure? you may assume constant specific heat. properties at 298 k and 1 atm:

Answers

Q is the heat transferred, m is the mass, C is the specific

PV = nRT

where P is the pressure, V is the volume, n is the number of moles, R is the gas constant, and T is the temperature. Since we are given the pressure and temperature of the system, we need to find the volume and number of moles of gas.

First, we can find the number of moles of hydrogen that dissociates from the H₂ gas. If the mole fraction of H is 5%, then the mole fraction of H₂ is 95%. Let's assume we start with 1 mole of H₂ . Then, we have:

0.05 moles of H

0.95 moles of H2

Some of the H₂ gas dissociates to H, so let's say x moles of H₂ dissociate. Then, we have:

(0.05 + x) moles of H

(0.95 - x) moles of H₂

Since we are assuming that the only final product is H₂, we know that all of the H atoms will recombine to form H₂:

(0.05 + x - 2x) moles of H₂

(0.95 - x) moles of H2

Simplifying this, we get:

(0.05 - x) moles of H₂

(0.95 - x) moles of H₂

Since we started with 1 mole of H₂, we know that the total number of moles is:

(0.05 - x) + (0.95 - x) = 1 - 2x

Now, we can use the ideal gas law to find the volume of gas at the final pressure and temperature. Since we know the number of moles of gas and the temperature, we just need to find the volume. We can rearrange the ideal gas law to get:

V = (nRT)/P

At 298 K and 1 atm, the gas constant R is 0.08206 L·atm/(mol·K). So, for the initial conditions, we have:

V_initial = (1 mol * 0.08206 L·atm/(mol·K) * 298 K) / 1 atm = 24.4658 L

Now, we can use the mole fractions and the number of moles to find the final volume of gas. We have:

(0.05 - x) moles of H₂

(0.95 - x) moles of H₂

The total number of moles is 1 - 2x, so we have:

(0.05 - x)/(1 - 2x) moles of H₂

(0.95 - x)/(1 - 2x) moles of H₂

Using the ideal gas law again, we can find the final volume:

V final = [(0.05 - x)/(1 - 2x) + (0.95 - x)/(1 - 2x)] * (0.08206 L·atm/(mol·K) * T) / 1.1 atm

Simplifying this, we get:

V final = [1 - 2x] * (0.08206 L·atm/(mol·K) * T) / (1.1 atm)

Now, we need to use the fact that the specific heat is constant to find the final temperature. We can use the formula:

Q = mCΔT

where Q is the heat transferred, m is the mass, C is the specific

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water (h2o) is a polar solvent and hexane (c6h14) is a nonpolar solvent. in which solvent is hf likely to dissolve?

Answers

HF, or hydrogen fluoride, is likely to dissolve in water (H2O), a polar solvent.

This is due to the principle "like dissolves like," which means that polar solvents tend to dissolve polar solutes, and nonpolar solvents tend to dissolve nonpolar solutes.  HF is a polar molecule because of the difference in electronegativity between hydrogen (H) and fluorine (F) atoms, resulting in a polar covalent bond. This bond creates a dipole moment, causing the HF molecule to have a partial positive charge on the hydrogen end and a partial negative charge on the fluorine end.

Water, as a polar solvent, has a similar dipole moment due to the difference in electronegativity between oxygen (O) and hydrogen (H) atoms. The partial positive charges on the hydrogen atoms in water molecules can interact with the partial negative charges on the fluorine atoms in HF molecules, forming hydrogen bonds. These interactions between polar molecules make it possible for HF to dissolve in water.


In conclusion, HF is likely to dissolve in water (H2O) because both are polar substances that can form hydrogen bonds, following the "like dissolves like" principle.

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GEN CHEM 2 PLEASE HELP

Answers

When Q < K (the reaction quotient is less than the equilibrium constant), the reaction will proceed in the forward direction to reach equilibrium. The correct response is option C

What happens when Q < K or Q = K in a reaction?

When Q = K (the reaction quotient is equal to the equilibrium constant), the reaction is at equilibrium and the concentrations of the reactants and products will remain constant over time.

At equilibrium, the rates of the forward and reverse reactions are equal and there is no net change in the concentrations of the reactants and products.

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carboxylic acids are typically prepared using oxidation reactions. which of the functional groups below can be oxidized to give a carboxylic acid product? select all that apply.

Answers

The functional groups that can be oxidized to give a carboxylic acid product are:

Primary alcoholsAlkynes. Options A and D are correct.

Carboxylic acids can be prepared by oxidizing a variety of functional groups. However, not all functional groups can be oxidized to give a carboxylic acid product. In general, primary alcohols and alkynes are two types of functional groups that can be oxidized to give a carboxylic acid.

Primary alcohols are oxidized to carboxylic acids via an intermediate aldehyde using a strong oxidizing agent such as potassium permanganate (KMnO₄) or chromium trioxide (CrO₃). The aldehyde is then further oxidized to the corresponding carboxylic acid.

Alkynes, on the other hand, can be oxidized directly to carboxylic acids using a strong oxidizing agent such as ozone (O₃) or potassium permanganate (KMnO₄). Phenols and secondary alcohols, however, cannot be directly oxidized to carboxylic acids. Phenols can be oxidized to quinones, while secondary alcohols can be oxidized to ketones, but these products are different from carboxylic acids.

The complete question is

Carboxylic acids are typically prepared using oxidation reactions. Which of the functional groups below can be oxidized to give a carboxylic acid product? Select all that apply.

A) Primary alcohols

B) Phenols

C) Secondary alcohols

D) Alkynes

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if 9.97 g of nacl reacts with excesses of the other reactants and 3.77 g of nahco3 is isolated, what is the percent yield of the reaction?

Answers

The percent yield of the reaction is 52.6%. The balanced chemical equation for the reaction between NaCl and NaHCO3 is:

2 NaCl + NaHCO3 → Na3CO3 + H2O + CO2

The molar mass of NaCl is 58.44 g/mol, and 9.97 g of NaCl corresponds to 9.97 g / 58.44 g/mol = 0.1705 mol of NaCl.

According to the equation, 1 mole of NaCl reacts with 1/2 mole of NaHCO3. So, the amount of NaHCO3 needed to react completely with 0.1705 mol of NaCl is:

0.1705 mol NaCl x (1/2) mol NaHCO3 = 0.08525 mol NaHCO3

The actual amount of NaHCO3 isolated is 3.77 g / 84.01 g/mol = 0.0449 mol NaHCO3.

The percent yield of the reaction is:

(actual yield / theoretical yield) x 100%

= (0.0449 mol / 0.08525 mol) x 100%

= 52.6%

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in order for the reaction shown to occur, the procedure calls for the addition of sulfuric acid to nitric acid. what might be the consequence of adding nitric acid to the sulfuric acid instead? the nitration would occur exclusively at the meta position. the nitration would occur exclusively at the ortho position. there are no regioselectivity or safety consequences. the exothermic reaction could cause the concentrated acid to boil.

Answers

Adding nitric acid to sulfuric acid could cause the concentrated acid to boil, potentially leading to safety hazards.

The result of adding nitric corrosive to sulfuric corrosive rather than the opposite way around is that the exothermic response could make the concentrated corrosive bubble, possibly prompting security risks. Nitration responses regularly require a combination of sulfuric corrosive and nitric corrosive as the nitrating specialist, as the sulfuric corrosive goes about as an impetus to produce the electrophilic nitrating species. Assuming that nitric corrosive were added first, the concentrated sulfuric corrosive might actually bubble, which could bring about the deficiency of reactants, decline in yield, and posture wellbeing perils because of the potential for arrival of harmful exhaust and additionally blast.

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lucas adds 10g of table salt and 20g of sand to 50 g of distilled water the mixture is then stirred for 1 hour which technique will allow lucas to separate the mixture

Answers

The filtration technique can be used by Lucan to separate the mixture.

Filtering is a physical separation procedure that uses a filter media with a complicated structure that only allows fluid to flow through it to separate solid particles and liquid from a combination. Filtrate is the term for the fluid that passes through large solid particles that cannot pass through the filter medium.

The procedure for utilizing filtration to separate the mixture is as follows:

Filter paper should be placed in a funnel and wetted with distilled water.Put a beaker on top of the funnel.Through the filter paper, pour the salt, sand, and water combination.Although the salt and water flow through and are collected in the beaker, the sand will be held on the filter paper.Lucas can use the evaporation method to separate the salt and water. A flame may be used to heat the beaker containing the saltwater solution, which will cause the water to evaporate and leave the salt behind.

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What group are the alkali metals on the periodic table?

Answers

Answer: group 1A (or IA)

Explanation:

Alkali metals are Group 1

1. Which statement is correct about intermolecular versus intramolecular forces?
Intramolecular forces exist within a single molecule. Covalent bonding is an example.
Intermolecular forces exist within a single molecule. Hydrogen bonding is an example.
Intermolecular forces exist between separate molecules. Covalent bonding is an example.
Intramolecular forces exist between separate molecules. Hydrogen bonding is an example.

Answers

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What is the frequency of electromagnetic radiation with wavelength 532 nm. C = 3.00 * 10^17 nm/s a. 5.64 x 10^14 s^-1 b. 6.48 x 10^12 s^-1 c. 4.18 x 10^18 s^-1 d. 6.23 x 10^14 s^-1 e. 3.75 x 10^15 s^-1

Answers

The frequency of electromagnetic radiation with wavelength 532 nm is [tex]5.64 x 10^14 s^-1[/tex]. The correct option is (a).

According to the equation c = λν,

where c is the speed of light,

λ is the wavelength,

and ν is the frequency of the wave.

We have been given,

λ = 532 nm = [tex]532 x 10^-9 m[/tex] (since, 1 nm = 10^-9 m)

[tex]c = 3.00 x 10^8 m/s[/tex]

By substituting the values in the equation,

[tex]c = λν3.00 x 10^17 s^-1 = (532 x 10^-9 m)[/tex]

[tex]νν = (3.00 x 10^17 s^-1)/(532 x 10^-9 m)ν = 5.64 x 10^14 s^-1[/tex]

Therefore, the frequency of electromagnetic radiation with wavelength 532 nm is [tex]5.64 x 10^14 s^-1[/tex]. The correct option is (a).

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3.5 grams of Nitrogen is allowed to react with 3.5 grams of Hydrogen to produce 5.6 L of Ammonia according to the following formula:
N2 + 3H2 →
2NH3
Which substance is the limiting reactant?
A.H2
B.N2
C.NH3
D.All reactants are completely used during this reaction.

Answers

B. N2 is the limiting reactant. The reactant that has the smaller number of moles in the balanced equation is the limiting reagent.

What is Limiting Reagent?

The limiting reagent is the reactant that is entirely consumed when the reaction goes to completion, and thus limits the amount of product that can be formed. The other reactants that are present in excess are not entirely consumed and do not limit the amount of product that can be formed.

To determine the limiting reactant, we need to calculate the amount of product that can be produced from each reactant and then choose the reactant that produces the smallest amount of product.

The balanced equation for the reaction is:

N2 + 3H2 → 2NH3

The molar mass of N2 is 28 g/mol, and the molar mass of H2 is 2 g/mol. Using these values, we can calculate the number of moles of each reactant:

Number of moles of N2 = 3.5 g / 28 g/mol = 0.125 mol

Number of moles of H2 = 3.5 g / 2 g/mol = 1.75 mol

According to the balanced equation, 1 mole of N2 reacts with 3 moles of H2 to produce 2 moles of NH3. So, the number of moles of NH3 that can be produced from each reactant is:

Moles of NH3 produced from N2 = 0.125 mol × (2 mol NH3 / 1 mol N2) = 0.25 mol NH3

Moles of NH3 produced from H2 = 1.75 mol × (2 mol NH3 / 3 mol H2) = 1.17 mol NH3

Therefore, the limiting reactant is N2, since it produces a smaller amount of NH3 compared to H2.

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